多孔氮化硅高温氧化特性分析

采用TG-DSC、XRD、SEM、ICP 等分析手段,对某一典型多孔氮化硅样品进行4 个不同温度点的

静态和微动态连续氧化试验,最高氧化温度为1 400℃。结果表明:多孔氮化硅在0. 1 MPa 静态空气气氛下,

800℃之前,氧化反应非常微弱,800℃以上可见明显的氧化反应,1 000℃以上氧化反应加剧,增重速率加快,并

优先发生在表面与外部孔壁处,之后再发生在样品的内部孔隙处,氧化反应受界面处的化学动力学控制,以被

动氧化为主,主要生成物是SiO2,属吸热反应。当生成的SiO2 将氮化硅表面和孔壁处覆盖时,在其界面处,随

着温度的进一步升高或时间的延长,会生成Si2N2O,且需要注意防范样品可能出现脆性断裂情况。此外,同等

温度下,动态氧化气氛将加速氮化硅的氧化,特别是多孔和粉末状样品。

     

Study on the Deformation Behavior of Mg-Gd-Y-Zn-Mn Wrought Magnesium Alloys by Visco-plastic Self-consistent Modeling

The plastic deformation behavior of new Mg-Gd-Y-Zn-Mn magnesium alloys gains great necessity to clarify and understand the mechanism deeply. In the present work， the tensile mechanical property test and visco-plastic self-consistent (VPSC) model are used to investigate the activities of deformation modes of VW84M and VW94M magnesium alloys during the tensile deformation. The results show that the mechanical properties of the above extruded alloys are similar but VW94M has higher strength than VW84M after the same aging process. Compared with the extruded alloys， the as-aged alloys have significantly higher activation of pyramidal slip at the later stage of plastic deformation. In addition， the as-aged VW94M alloy with higher strength has the largest activity of pyramidal slip. In summary， the addition of Gd increases the critical resolved shear stress (CRSS) in each slip system of VW94M， while the increase in the strength and the decrease in the elongation of as-aged alloys are associated with the significant activation of pyramidal slip.     

不同晶体取向单晶锗的力学性能

为了研究微纳米尺度下单晶锗的力学特性,采用纳米压痕仪对单晶锗(100)(110)和(111)晶面进行了纳米压痕实验,并通过原子力显微镜对材料表面进行了观测。根据单晶锗各晶面的位移-载荷曲线,对单晶锗各晶面的弹性回复率、硬度、弹性模量与压入深度之间的关系进行了分析。结果表明:单晶锗在加载过程中分别经历了弹性变形、塑性变形和脆性变形三个阶段。当压入深度超过500 nm时,加载曲线上有突进点产生;当压入深度超过100 nm时,卸载曲线上有突退点产生。单晶锗的残余压痕形貌表现为凸起状,表明单晶锗具有较低的加工硬化趋势。当压入深度达到100 nm时,单晶锗表现出明显的尺寸效应,且单晶锗(111)晶面具有最低硬度和弹性模量值。表明相对于其他两个晶面,单晶锗(111)晶面具有更好的塑性变形能力。     

On a plastic instability criterion for ultra-large radial-axial ring rolling process with four guide rolls

A dynamic mechanical model is proposed to describe the complexing actions of all the rolls on the ring during the ultra-large radial-axial ring rolling(RARR) process with four guide rolls. Based on the model, the calculation models for bending moment and normal stress at any section of the ring are deduced by force method. If the maximum section bending normal stress exceeds the yield stress of the ring materials, the ring will be distorted thus leading to the instability of the RARR process. Ac...     

Biaxial tensile behavior of Ti-6Al-4V under proportional loading

The biaxial tensile behavior of isotropic Ti-6Al-4 V is characterized in this paper. A novel cruciform specimen was designed and optimized to achieve uniform stress and strain distribution within the gauge area. Biaxial tensile tests were conducted at three different loading ratios by the biaxial testing machine. The Digital Image Correlation (DIC) technique was applied to determine strain distribution, and a high-speed camera was employed to record the fracture process. An Inverse Analysis (IA) approach with a combined experimental and numerical method was proposed to determine the true stresses at the gauge section of the specimen during biaxial tensile tests. The results indicate that the initial yield locus can be described by the Cazacu criterion accurately, whereas the Mises criterion can predict better the strengthening behavior of Ti-6Al-4 V in the first quadrant in the principal stress space.     

Experimental and numerical investigation of mechanical behavior of plain woven CFRP composites subjected to three-point bending

The mechanical behavior of plain woven Carbon Fiber-Reinforced Polymer (CFRP) composites under Three-Point Bending (TPB) is investigated via experimental and numerical approaches. Multiscale models, including microscale, mesoscale and macroscale models, have been developed to characterize the TPB strength and damages. Thereinto, Representative Volume Elements (RVEs) of the microscale and mesoscale structures are established to determine the effective properties of carbon-fiber yarn and CFRP composites, respectively. Aimed at accurately and efficiently predicting the TPB behavior, an Equivalent Cross-Ply Laminate (ECPL) cell is proposed to simplify the inherent woven architecture, and the effective properties of the subcell are computed using a local homogenization approach. The macroscale model of the TPB specimen is constructed by a topology structure of ECPL cells to predict the mechanical behavior. The TPB experiments have been performed to validate the multiscale models. Both the experimental and numerical results reveal that delamination mainly appears in the top and bottom interfaces of the CFRP laminates. And matrix cracking and delamination are identified as the significant damage modes during the TPB process. Finally, the quasi-static and dynamic behaviors of plain woven composites are discussed by comparing the results of Low-Velocity Impact (LVI) and TPB simulations.     

Local empirical model of ionospheric variability

The paper presents an analysis of the ionospheric variability as a function of local time, month, and geomagnetic activity level. The 2003–2020 dataset of peak electron densities (NmF2) from the Irkutsk DPS-4 Digisonde (52.3°N, 104.3°E) was converted into the dataset of the NmF2 disturbances (ΔNmF2) representing the relative (percentage) deviations of the NmF2 from the 27-day running median. The ΔNmF2 dataset was used to calculate root mean square values of ΔNmF2 (σNmF2) by 27-day running averaging. These σNmF2 values were considered as a measure of ionospheric variability. The σNmF2 as function of local time, day of year, and year was the input for building the local empirical model of ionospheric variability based on the linear regression of σNmF2 on the 27-day average daily Ap-index of geomagnetic activity. The paper demonstrates the diurnal-seasonal variations in σNmF2 under low geomagnetic activity (linear regression intercept) as well as the rate of increase/decrease in σNmF2 with increasing Ap (linear regression slope). The obtained diurnal, seasonal, and geomagnetic activity behavior of σNmF2 is compared with previous studies of ionospheric variability.     

新型SiBCN杂化树脂的固化及裂解机理

以硅乙烯基1,7-碳硼烷为B源与含乙烯基硅氮烷反应生成了一种新型的SiBCN杂化树脂。采用FT-IR、DSC、TGA和Py GC-MS对树脂的结构、固化行为、热稳定性、热裂解反应和过程进行了研究,并用Kissinger方程和FWO法计算出了固化反应和热裂解的表观活化能,分析了树脂的裂解过程及机理。结果表明:这种杂化树脂在固化过程中存在一个放热峰,固化表观活化能为113.55 k J/mol,具有较好的热稳定性,N_2气氛下,T_d~5为459℃,900℃下的残碳率为73.1%。随着裂解反应程度的增加,树脂裂解的表观活化能增加,动力学热稳定性增强。当裂解温度为300℃时,树脂主要发生转氨基反应,裂解产生NH_3;500℃时,有机基团脱除,树脂裂解产生NH_3、CH_4和CH_2=CH_2等烯烃;650℃时,裂解气体种类进一步增加,生成一系列烷烃和烯烃。     

TC4钛合金切削中切屑塑性变形分析

对TC4钛合金切削过程中锯齿形切屑形成过程和切削力的关系进行了实验研究,并对锯齿形切屑形成中微观塑性变形区进行了分析。结果表明:当切削速度大于48.75 m/min时,切屑由带状转变为锯齿形。锯齿形切屑的形成导致了切削过程中切削力的波动变化,切削力与切屑的锯齿形变化规律一致,锯齿形切屑形成中塑性变形区的宽度随切削速度的增加而减小。     

Optimum alternate material selection methodology for an aircraft skin

Weight penalty has been a challenge for design engineers of aerospace vehicles. Today’s high-efficiency combat aircraft undergoes intense stress and strain during flying missions, which require stronger and stiffer materials to retain structural integrity. Though metallic materials have been successfully used for the construction of aircraft structures and components, metals still have a low strength-to-weight ratio. This paper aims to develop an alternate optimised material selection methodolog...